Chemical blowing agents for the fabrication of nitrogen and oxygen co-doped carbon nanofibers: Structural and supercapacitive study

Aydin H., Ustun B., ŞAHİNTÜRK U., KOÇ S. N., KURTAN Ü.

JOURNAL OF POWER SOURCES, cilt.626, 2025 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 626
  • Basım Tarihi: 2025
  • Doi Numarası: 10.1016/j.jpowsour.2024.235756
  • Dergi Adı: JOURNAL OF POWER SOURCES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, INSPEC, Metadex, Pollution Abstracts, Civil Engineering Abstracts
  • İstanbul Üniversitesi-Cerrahpaşa Adresli: Evet

Özet

Here, two kinds of chemical blowing agents (BAs), specifically, oxy-bis (benzene sulfonyl) hydrazide (OBSH), and azodicarbonamide (ADC) have been explored in the fabrication of carbon nanofibers for potential usage as the electrode materials in supercapacitors (SCs). The BAs are not only used as poring agents but also as heteroatom dopants. The type and the amount of BAs are significant to obtain a good porous carbon nanofiber structure and a low amount of usage provided a better nanostructure including a larger surface area (492.5 m2/g), a better total volume (0.216 cm3/g), higher level of structural disorder and defects (ID/IG, 1.02), and higher heteroatom content (5.26 at% N and 10.38 at% O) for C/OBSH-10 nanofiber. The symmetrical SC composed of C/OBSH-10 nanofiber electrode offers a specific energy of 6.2 Wh/kg at a specific power of 300 W/kg. Moreover, the cycling ability is superior (94.6 %) after 10,000 charge-discharge test and this work can be a strategy to obtain other porous carbon-based materials for energy storage applications.