Synthesis and characterization of novel HMPM bridged ball-type metallophthalocyanines, and their DFT studies and electrochemical performance as supercapacitor electrodes

Koçyiğit N., Arvas M. B., Yazar S., Açar-Selçuki N., Şahin Y., Özer M., ...More

SYNTHETIC METALS, vol.292, pp.117242, 2023 (SCI-Expanded, Scopus) identifier identifier

  • Publication Type: Article / Article
  • Volume: 292
  • Publication Date: 2023
  • Doi Number: 10.1016/j.synthmet.2022.117242
  • Journal Name: SYNTHETIC METALS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Chemical Abstracts Core, Communication Abstracts, INSPEC, Metadex, Civil Engineering Abstracts
  • Page Numbers: pp.117242
  • Istanbul University-Cerrahpasa Affiliated: Yes

Abstract

Novel 4, 4'-((((2-(3, 4-dicyanophenoxy)-5-methyl-1, 3-phenylene) bis (methylene)) bis (4-methyl-3, 1-phenylene)) bis (oxy)) -bridged ball-type phthalocyanines were achieved from 4, 4' -((((2-(3, 4-dicyanophenoxy)-5methyl-1, 3-phenylene) bis (methylene)) bis (4-methyl-3, 1-phenylene)) bis (oxy)) diphthalonitrile through appropriate transition metal (II) acetate salts in 2-dimethylaminoethanol. The new tris-phthalonitrile precursor was achieved from 3,3'-((2-hydroxy-5-methyl-1,3-phenylene) bis (methylene)) bis (4-methylphenol), and 4nitrophthalonitrile with the presence of catalyst potassium carbonate in dimethylformamide at 50.C. The structural verification of the compounds was accomplished by proton-nuclear magnetic resonance, matrixassisted laser desorption/ionization time-of-flight mass, infrared, and ultraviolet-visible spectroscopic methods. The BTCuPc electrode material exhibited a specific capacitance of 265 F.g 1 at a scan rate of 5 mV.s 1 in 3.0 M KCl aqueous electrolyte. In addition, a wide operating potential range (1.5 V) was achieved in the aqueous electrolyte.