New Piperazine Derivatives Synthesized from Thio-Substituted Polyhalogeno-2-nitro-1,3-butadienes
E-JOURNAL OF CHEMISTRY, cilt.7, sa.4, ss.1498-1506, 2010 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 7 Sayı: 4
- Basım Tarihi: 2010
- Doi Numarası: 10.1155/2010/605760
- Dergi Adı: E-JOURNAL OF CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.1498-1506
- Anahtar Kelimeler: Monothio-substituted nitrodiene, Piperazine, N,S-substituted nitrobutadiene, X-ray analysis, POLYHALOGENATED NITROBUTADIENES, AZOLYL DERIVATIVES, NITROHALOBUTADIENES, ARYLPIPERAZINES, CHEMISTRY
- Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
- İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır
Özet
It is known that polyhalogeno-nitro-1,3-butadienes are important starting materials for the synthesis of polyfunctionalized bioactive heterocycles. Novel N, S-substituted nitrobutadienes (4a-j) were synthesized from the reaction of the monothio-substituted nitrodiene derivatives (2a) and (2b) with some piperazine derivatives. These new compounds are stable and the structures of these products were characterized by spectroscopic data. The structure of the novel N, S-substituted nitrodiene compound (4g) synthesized in this study was also elucidated by single crystal x-ray analysis.