Thiourea-assisted nitrogen and sulfur dual-doped carbon nanofibers for enhanced supercapacitive energy storage

Üstün B., Aydın H., Koç S. N., Kurtan Ü.

JOURNAL OF MATERIALS SCIENCE: MATERIALS IN ELECTRONICS, cilt.34, ss.408, 2023 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 34
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1007/s10854-023-09843-4
  • Dergi Adı: JOURNAL OF MATERIALS SCIENCE: MATERIALS IN ELECTRONICS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Aerospace Database, Applied Science & Technology Source, Chemical Abstracts Core, Communication Abstracts, Compendex, Computer & Applied Sciences, INSPEC, MEDLINE, Metadex, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.408
  • İstanbul Üniversitesi-Cerrahpaşa Adresli: Evet

Özet

Herein, using thiourea is a simple and effective approach to produce the unique structure constructed by N and S dual-doped carbon nanofibers. The surface porosity is optimized by changing the thiourea amount in the polymer solution. The optimized N/S-CNF5, which the weight percentage of thiourea to polyacrylonitrile is 5, has a high specific surface area (144.2 m(2) g(-1)) and rich content of heteroatoms (N-4.66 at% and S-0.11 at.%), respectively. Because of these unique features, N/S-CNF5 demonstrates a large gravimetric-specific capacitance (312 F g(-1) at 10 mV s(-1) and 225 F g(-1) at 1 A g(-1)). The N/S-CNF5 electrode represents in the two-electrode system with a high specific capacitance of 160 F g(-1) at 1 A g(-1) and shows a remarkable rate of performance (87.5% retention) even at 5 A g(-1). Moreover, the symmetrical supercapacitor device (N/S-CNF5//N/S-CNF5) delivers specific energy of as high as 5.5 Wh kg(-1) with a specific power of 250 W kg(-1). Also, the device's cycling ability is 78.3% even after 30 000 cycles at 1 A g(-1). This strategy can be feasible to explore more dual heteroatom-doped carbon nanomaterials for a wide range of electrochemical applications.