Thermal decomposition of N-1,N-4-diarylidene-S-methylthiosemicarbazone dioxouranium(VI) templates


Bal T., Ulkuseven B.

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, cilt.49, sa.11, ss.1685-1688, 2004 (SCI-Expanded, Scopus) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 49 Sayı: 11
  • Basım Tarihi: 2004
  • Dergi Adı: RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1685-1688
  • İstanbul Üniversitesi-Cerrahpaşa Adresli: Evet

Özet

The solvated dioxouranium(VI) complexes [UO2(L)S] (S = H2O, methyl, ethyl-, iso-amyl-, n-octyl- and n-undecyl-alcohol) were prepared from salicyl- and 5-bromosalicylaldehyde S-methylthiosemicarbazones. The templates were characterized by elemental analysis, IR and UV-Vis spectroscopy, magnetic susceptibility, and molar conductivity. The thermal stability of the compounds was investigated in air depending on the solvent molecule.