The Synthesis of New S- and N,S-Substituted Halo Nitro Dienes by the Reactions of 1-Bromo-1,2,4,4-tetrachloro-3-nitrobuta-1,3-diene with Thiols and Cyclic Amines
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.185, sa.10, ss.2014-2023, 2010 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 185 Sayı: 10
- Basım Tarihi: 2010
- Doi Numarası: 10.1080/10426500903453318
- Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.2014-2023
- Anahtar Kelimeler: Halides, nitro compounds, nucleophilic substitutions, piperazine derivatives, thiols, NITROBUTADIENES, THIOETHERS, CHEMISTRY, DITHIOLS, AGENTS
- İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır
Özet
The substituted products alkyl(aryl)thio-tetrahalo-3-nitrobuta-1,3-dienes 3a-b were obtained from the reactions of 1-bromo-1,2,4,4-tetrachloro-3-nitrobuta-1,3-diene (1) with thiols. Further reactions of the substituted product alkyl(aryl)thio-tetrahalo-3-nitrobuta-1,3-dienes 3a-b in dichloromethane reacted with piperazine derivatives and morpholine to generate 5a-b and 7a-l. The structures of the new compounds were determined by microanalysis and spectroscopic data.