Optimizing Oxygen Electrode Bifunctionality with Platinum and Nickel Nanoparticle-Decorated Nitrogen-Doped Binary Metal Oxides

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Mladenović D., Aykut Y., BAYRAKÇEKEN YURTCAN A., Soylu G. S., Santos D. M. F., Miljanić Š., ...Daha Fazla

Processes, cilt.12, sa.3, 2024 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 12 Sayı: 3
  • Basım Tarihi: 2024
  • Doi Numarası: 10.3390/pr12030453
  • Dergi Adı: Processes
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Aerospace Database, Communication Abstracts, INSPEC, Metadex, Directory of Open Access Journals, Civil Engineering Abstracts
  • Anahtar Kelimeler: bifunctional electrocatalyst, binary metal oxides, oxygen evolution reaction, oxygen reduction reaction, platinum and nickel nanoparticles
  • Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
  • İstanbul Üniversitesi-Cerrahpaşa Adresli: Evet

Özet

Developing bifunctional oxygen electrode materials with superior activity for oxygen reduction (ORR) and oxygen evolution (OER) reactions is essential for advancing regenerative fuel cell and rechargeable metal–air battery technologies. This present work deals with the synthesis and characterization of electrocatalysts containing Pt and Ni nanoparticles supported on nitrogen-doped mixed metal oxides (Mn2O3-NiO) and the systematic evaluation of their bifunctional ORR/OER performance in an alkaline medium. These electrocatalysts have been successfully synthesized by a simple and fast microwave method. PtNi/Mn2O3-NiO-N with a binary metal oxide-to-N ratio of 1:2 demonstrated the best performance among the studied materials regarding bifunctional electrocatalytic activity (∆E = 0.96 V) and robust stability.