The reactions of some alkyl(thio)-substituted 2-nitrodienes with piperazines and a structural study

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Ibis C., Sayil C., Ozkok F.

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, cilt.61, sa.9, ss.1174-1179, 2006 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 61 Sayı: 9
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1515/znb-2006-0921
  • Dergi Adı: ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1174-1179
  • Anahtar Kelimeler: thiosubstituted nitrodiene, N,S-substituted nitrodienes, piperazine derivatives, HETEROCYCLIC-COMPOUNDS, PRIMARY AMINES, DIENES, 2-NITROPENTACHLORO-1,3-BUTADIENE, NITRODIENES, PERCHLOROBUTENYNE, ARYLPIPERAZINES, DITHIOLS, THIOLS
  • Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
  • İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır

Özet

Thiosubstituted nitrodiene compound la was obtained from 2-nitropentachlorobutadiene and dodecanethiol. Compound 1b was prepared from 2-nitropentachlorobutadiene and hexadecanethiol. Monosubstituted diene compounds la and 1b reacted with piperazines such as derivatives of 2 and 4 in CH2Cl2 and gave the novel compounds. 2-Nitro-3,4,4-trichloro-1-dodecylthio-1-(2-fluorophenylpiperazinyl]-1,3-butadiene (3d) was synthesized and its crystal structure was determined.