The reactions of some alkyl(thio)-substituted 2-nitrodienes with piperazines and a structural study
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, cilt.61, sa.9, ss.1174-1179, 2006 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 61 Sayı: 9
- Basım Tarihi: 2006
- Doi Numarası: 10.1515/znb-2006-0921
- Dergi Adı: ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.1174-1179
- Anahtar Kelimeler: thiosubstituted nitrodiene, N,S-substituted nitrodienes, piperazine derivatives, HETEROCYCLIC-COMPOUNDS, PRIMARY AMINES, DIENES, 2-NITROPENTACHLORO-1,3-BUTADIENE, NITRODIENES, PERCHLOROBUTENYNE, ARYLPIPERAZINES, DITHIOLS, THIOLS
- Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
- İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır
Özet
Thiosubstituted nitrodiene compound la was obtained from 2-nitropentachlorobutadiene and dodecanethiol. Compound 1b was prepared from 2-nitropentachlorobutadiene and hexadecanethiol. Monosubstituted diene compounds la and 1b reacted with piperazines such as derivatives of 2 and 4 in CH2Cl2 and gave the novel compounds. 2-Nitro-3,4,4-trichloro-1-dodecylthio-1-(2-fluorophenylpiperazinyl]-1,3-butadiene (3d) was synthesized and its crystal structure was determined.