SYNTHESIS AND CHARACTERIZATION OF NITROGEN AND SULFUR CONTAINING 1,4-NAPHTHOQUINONES
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.188, sa.12, ss.1855-1867, 2013 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 188 Sayı: 12
- Basım Tarihi: 2013
- Doi Numarası: 10.1080/10426507.2013.796475
- Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.1855-1867
- İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır
Özet
New N,S-disubstituted naphthoquinones were synthesized by reactions of S- and N-nucleophiles with 2,3-dichloro-1,4-naphthoquinone. 2-(Hexadecylthio)-3-(phenylamino)-naphthalene-1,4-dione 5a was synthesized by reaction of 2-chloro-3-(phenylamino)-naphthalene-1,4-dione 3a with hexadecanethiol 4a. The structures of the new synthesized naphthoquinone derivatives were determined by micro analyses and spectroscopic methods (FT-IR, H-1 NMR, C-13 NMR, MS, and UV/Vis.). Photo- and electrochemical properties of selected compounds were investigated by using fluorescence spectroscopy and the cyclovoltammetry method.