Chiral cyclometalated iridium complexes for asymmetric reduction reactions.
Organic & biomolecular chemistry, cilt.19, ss.279-284, 2021 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 19
- Basım Tarihi: 2021
- Doi Numarası: 10.1039/d0ob02049d
- Dergi Adı: Organic & biomolecular chemistry
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Compendex, EMBASE, MEDLINE, Veterinary Science Database
- Sayfa Sayıları: ss.279-284
- İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır
Özet
A series of chiral cyclometalated iridium complexes have been synthesised by cyclometalating chiral 2-aryl-oxazoline and imidazoline ligands with [Cp*IrCl2](2). These iridacycles were studied for asymmetric transfer hydrogenation reactions with formic acid as the hydrogen source and were found to display various activities and enantioselectivities, with the most effective ones affording up to 63% ee in the asymmetric reductive amination of ketones and 77% ee in the reduction of pyridinium ions.