The hydrogenation of 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF) with sol-gel Ru-Co/SiO2 catalyst

Esen M., Akmaz S., Koc S. N., GUERKAYNAK M. A.

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, cilt.91, sa.3, ss.664-672, 2019 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 91 Sayı: 3
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1007/s10971-019-05047-7
  • Dergi Adı: JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.664-672
  • Anahtar Kelimeler: Biofuel, HMF, DMF, Catalytic hydrogenation, Sol-gel catalyst, FISCHER-TROPSCH SYNTHESIS, SELECTIVE HYDROGENATION, HIGH-TEMPERATURE, BIOMASS, FUELS, CO/SIO2, HYDROGENOLYSIS, RU, TRANSFORMATION, HYDROCARBONS
  • İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır

Özet

Sol-gel Ru/SiO2, Co/SiO2, and Ru-Co/SiO2 catalysts were prepared for 5-hydroxymethylfurfural (HMF) hydrogenation to 2,5-dimethylfuran (DMF). Catalysts were characterized by BET, XRD, TPR, TEM, and XPS. Reactions were run with catalysts that were reduced at 500 degrees C for 1h. Reaction time, temperature and hydrogen pressure effects were studied for hydrogenation. In the presence of both Ru and Co, the easier reduction was observed at Ru-Co/SiO2 catalyst. Although no DMF yield was observed with Ru/SiO2 and Co/SiO2, 96% DMF was obtained at 180 degrees C, under 15bar H-2 pressure for 2h. Moreover >99.9% DMF yield was achieved with Ru-Co/SiO2 at 120 degrees C for 8h and at 140 degrees C for 4h, respectively. DMF yield did not change significantly after third use, however deactivation was observed after fifth use of catalyst. It may be attributed to oxidation of cobalt active sites during recycle runs.