An investigation of nucleophilic substitution reactions of 2,3-dichloro-1,4-naphthoquinone with various nucleophilic reagents


Ibis C., Shntaif A. H., Bahar H., Ayla S.

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, cilt.80, sa.6, ss.731-738, 2015 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 80 Sayı: 6
  • Basım Tarihi: 2015
  • Doi Numarası: 10.2298/jsc141124021i
  • Dergi Adı: JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.731-738
  • Anahtar Kelimeler: 1,4-naphthoquinone, thioethers, amine, indolylquinones, ANTIBACTERIAL, DERIVATIVES, ANTIFUNGAL
  • İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır

Özet

Novel N-, N,S- and N,O-substituted naphthoquinone compounds were prepared by the reactions of 2,3-dichloro-1,4-naphthoquinone (1) and the corresponding nucleophiles in the presence of chloroform and triethylamine or an ethanolic solution of Na2CO3. The structures of the novel naphthoquinone compounds were characterized by microanalysis, FT-IR. H-1-NMR, C-13-NMR, MS and cyclic voltammetry.