Petrographic and Geochemical Analysis of Upper Cretaceous Phosphorites in Şemikan, Turkey and Gusmari, Albania: Insights into Depositional Environments and Palaeoceanographic Conditions


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Fociro A., Öztürk H., Sinojmeri A., Cansu Z., Moisiu L., Çelik Y.

EGU General Assembly 2024, Vienna, Avusturya, 14 - 19 Nisan 2024, ss.111, (Özet Bildiri)

  • Yayın Türü: Bildiri / Özet Bildiri
  • Basıldığı Şehir: Vienna
  • Basıldığı Ülke: Avusturya
  • Sayfa Sayıları: ss.111
  • İstanbul Üniversitesi-Cerrahpaşa Adresli: Evet

Özet

The Tethyan Phosphogenic Province is one of the widest of its kind, representing an outstanding

period of phosphate deposition principally in the Upper Cretaceous-Eocene period. The main aim

of this study is to compare the Turkish phosphorites occurring along the southern side of the Neo

Tethyan Ocean due to suitable seawater temperature and upwelling oceanic currents with

Albanian phosphorites were deposited in higher latitudes and colder climates, in the same ocean.

The Şemikan (Türkiye) phosphorites consist mainly of cream-coloured (CCP) and locally reddish

phosphorites (RP) occurring as lenses or concordant blankets within high-grade cream

phosphorites. Based on microscopic examination, cream-coloured phosphorites consist of

phosphatic pellets, intraclasts, bioclasts (fossilized shark teeth, ostracods etc.) and nonphosphatic

components, with texture changing from wackestone to packstone, testifying shallow marine

depositional environment. Whereas, Gusmari (Albania) phosphorites consist of laminated

phosphorites (LP), of mudstone/wackestone texture, with planktonic foraminifera

Globotruncanidae, where the phosphate is sedimentary, and alternating laminae of phosphate

and pelagic carbonate. Besides this, under SEM-EDS, 5μm crystals of the major ore of uranium,

UO2, were evidenced for the first time in LP. The mineralogical analyses showed that the CCP

consisted of carbonate-rich fluorapatite, minor calcite and quartz. The RP consisted predominantly

of carbonate-rich fluorapatite, hydroxyapatite, montmorillonite, and minor quartz. The LP

consisted predominantly of calcite, carbonate-rich fluorapatite, hydroxyapatite, and traces of

quartz. The mean P2O5 content of the CCP is 29%, RP and LP 14%, which is lower than that of other

well-known global phosphorite deposits. The CaO content of the CCP, RP and LP ore is also higher

than that of other global deposits because of a calcite matrix between phosphorite pellets. Based

on preliminary results of trace elements CCP, RP and LP show a general trace element scarcity

compared to the trace element averages of the world’s average phosphorites. The main reason for

this deficiency is the rapid sedimentation or high burial rate in the sedimentary basin, which

prevents the replacement of carbonate-rich fluorapatite by trace elements.