The synthesis and spectral characterization of novel nitrodiene compounds from thiols

Ibis C., Ozkok F.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.191, sa.1, ss.9-15, 2016 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 191 Sayı: 1
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1080/10426507.2015.1049742
  • Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.9-15
  • Anahtar Kelimeler: 1,3-Butadiene, thioester, thiols, single-crystal, N,S-substituted nitrodienes
  • İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır

Özet

Novel S-, S,S- and S,O-substituted nitrodiene compounds were synthesized from the reactions of 2-nitro-pentachloro-1,3-butadiene (1) and various thiols in different solvent media. The N,S-substituted nitrodienes also were achieved by the reactions of S-substituted nitrodienes with using morpholine, piperidine and piperazine derivatives. All of the new compounds were characterized by elemental analysis, UV-VIS, FT-IR, H-1-NMR, NMR and mass spectroscopy.