Recent Development in the Synthesis and Catalytic Application of Iridacycles
CHEMICAL RECORD, cilt.21, sa.6, ss.1506-1534, 2021 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 21 Sayı: 6
- Basım Tarihi: 2021
- Doi Numarası: 10.1002/tcr.202100051
- Dergi Adı: CHEMICAL RECORD
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aquatic Science & Fisheries Abstracts (ASFA), Biotechnology Research Abstracts, Chemical Abstracts Core, EMBASE, MEDLINE
- Sayfa Sayıları: ss.1506-1534
- Anahtar Kelimeler: cyclometallated complexes, iridacycles, hydrogenation, transfer hydrogenation, hydrosilylation, dehydrogenation, N-HETEROCYCLIC-CARBENE, CP-ASTERISK-IR, CHEMOSELECTIVE TRANSFER HYDROGENATION, METHODOLOGY COOPERATIVE CATALYSIS, ASYMMETRIC TRANSFER HYDROGENATION, CYCLOMETALATED IRIDIUM COMPLEXES, VERSATILE TRANSFER HYDROGENATION, DIRECT REDUCTIVE AMINATION, CARBOXYLIC-ACID SALTS, H-BOND ACTIVATION
- İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır
Özet
Cyclometallated complexes are well-known and have found many applications. This article provides a short review on the progress made in the synthesis and application to catalysis of cyclometallated half-sandwich Cp*Ir(III) complexes (Cp*: pentamethylcyclopentadienyl) since 2017. Covered in the review are iridacycles featuring conventional C,N chelates and less common metallocene and carbene-derived C,N and C,C ligands. This is followed by an overview of the studies of their applications in catalysis ranging from asymmetric hydrogenation, transfer hydrogenation, hydrosilylation to dehydrogenation.