Synthesis and cyclization reactions of novel benzo[a]phenazine- and phenoxazine-5-ones derivatives

Kurban S., DENİZ N. G., SAYIL Ç.

BULGARIAN CHEMICAL COMMUNICATIONS, cilt.48, ss.43-48, 2016 (SCI-Expanded, Scopus) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 48
  • Basım Tarihi: 2016
  • Dergi Adı: BULGARIAN CHEMICAL COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.43-48
  • Anahtar Kelimeler: Phenazine, Phenoxazine, Phenyl-1,2-diamine, 2-Aminophenol, Quinones, SPECTRAL PROPERTIES, QUINONE CHEMISTRY, BENZOQUINONES, 2,3-DICHLORO-1,4-NAPHTHOQUINONE, 1,4-NAPHTHOQUINONES, ANTIOXIDANT, DYES
  • İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır

Özet

In the present study we reported the cyclization reactions of 2-(alkylthio)-1,4-naphthoquinones to 6-(alkylthio) benzo[ a] phenazine-and phenoxazin-5-ones derivatives 5a-c and 7b-c, respectively and their structural studies. The reactions of 2-(alkylthio)-3-chloro-1,4-naphthoquinone 3a-c with phenyl-1,2-diamine 4 and 2-aminophenol 6 in ethanol in the presence of sodium carbonate (Na2CO3) were investigated. All new compounds were characterized on the basis of nuclear magnetic resonance spectroscopy (H-1-and C-13-NMR), mass spectrometry (MS), and fourier transform infrared spectroscopy (FT-IR). A probable mechanism for the formation of all reaction products was presented and detailed spectroscopic data of all compounds were given.