Tartaric acid assisted in-situ growth of CuO nanostructures over ITO substrate for the electrocatalytic detection of Sudan I

Tunesi M. M., Kalwar N. H., SOOMRO R. A., Karakus S., JAWAID S., ABRO M. I.

MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, cilt.75, ss.296-300, 2018 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 75
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1016/j.mssp.2017.12.001
  • Dergi Adı: MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.296-300
  • Anahtar Kelimeler: CuO, Tartaric acid, Sudan I, ITO substrate, ACETYL-L-CYSTEINE, VOLTAMMETRIC DETERMINATION, LIQUID-CHROMATOGRAPHY, PASTE ELECTRODE, FOOD SAMPLES, DYES, NANOPARTICLES, NANOWIRES, OXIDATION
  • İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır

Özet

The study explores the potential of newly developed ITO based electrode for the electro-catalytic detection of Sudan I. The ITO based electrode utilizes a dense layer of 2D CuO nanostructures as an effective electron-transfer facilitator which promotes the electro-catalytic sensing of Sudan I in aqueous solution. The in-situ growth of CuO nanostructures was achieved using simple hydrothermal route with the assistance of tartaric acid utilized as an effective template. The in-situ grown layer comprises of 2D CuO nanostructures with morphological features similar to flowers composed of sharp-flake like features. The electro-catalytic oxidation of Sudan I over the described electrode system demonstrated low-over potential value and excellent working stability with good analytical linearity in the range of 0.001-1.56 mu M. The ITO based electrode was found highly selective and sensitive towards Sudan I with limit of detection determined to be 1.2 x 10(-4) mu M (S/N = 3).