Zn(II) and Pd(II) complexes of thiosemicarbazone-S-alkyl esters derived from 2/3-formylpyridine

Kizilcikli I., Ulkuseven B., Dasdemir Y., Akkurt B.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.34, sa.4, ss.653-665, 2004 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 34 Sayı: 4
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1081/sim-120035948
  • Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
  • Sayfa Sayıları: ss.653-665
  • Anahtar Kelimeler: polydentate thiosemicarbazones, Zn(H) and Pd(II) complexes, METAL ION COMPLEXES, 2-ACETYLPYRIDINE THIOSEMICARBAZONES, 2-PYRIDINECARBOXALDEHYDE THIOSEMICARBAZONE, PALLADIUM(II) COMPLEXES, ANTIFUNGAL PROPERTIES, BIOLOGICAL-ACTIVITY, CRYSTAL-STRUCTURE, COPPER(II), SULFUR
  • İstanbul Üniversitesi-Cerrahpaşa Adresli: Evet

Özet

Representative S-methyl/ethyl-4-H/phenylthiosemicarbazones and their Zn(II) and Pd(II) complexes were synthesized. Characterization of the 1:1 complexes, [Zn(L)Cl-2], [Pd(L)Cl-2], and [Pd(L)Cl]Cl, was accomplished by means of elemental analyses, IR and H-1 NMR spectra. The multidentate S-alkyl thiosemicarbazones coordinate as mono-, bi-, or tridentate ligands depending on the types of the alkyl moiety and metal ion.