Efficient removal of ammoniacal nitrogen from textile printing wastewater by electrooxidation considering the effects of NaCl and NaOCl addition

Cifcioglu-Gozuacik B., Ergenekon S. M., Ozbey-Unal B., Balcik C., Karagunduz A., Dizge N., ...Daha Fazla

WATER SCIENCE AND TECHNOLOGY, cilt.84, sa.3, ss.752-762, 2021 (SCI-Expanded, Scopus) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 84 Sayı: 3
  • Basım Tarihi: 2021
  • Doi Numarası: 10.2166/wst.2021.261
  • Dergi Adı: WATER SCIENCE AND TECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Analytical Abstracts, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Chimica, Compendex, EMBASE, Environment Index, Geobase, MEDLINE, Pollution Abstracts, Public Affairs Index, Veterinary Science Database, Directory of Open Access Journals
  • Sayfa Sayıları: ss.752-762
  • İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır

Özet

In this study, electrooxidation (EO) process using graphite electrodes as electrode pairs was used for the removal of chemical oxygen demand (COD), ammoniacal nitrogen (NH4+-N), and color from real textile printing wastewater. The effect of solution pH, sodium chloride (NaCl) dosage, sodium hypochlorite (NaOCl), which is the oldest and still most important chlorine-based bleach, dosage, and oxidation time were investigated on the removal efficiencies. Operating conditions of EO reactor were applied to current density 1 mA/cm(2), distance between the electrodes: 2 cm, 150 min operation time, and stirring speed of 500 rpm. At optimum condition; pH 9.5, applied current desitiy 1 mA/cm(2), NaCl dosage of 8 g/L, NaOCl dosage of 44.4 mg/L and 150 min electrooxidation time, the obtained removal efficiencies were 86.5% and 91.1% for COD and ammoniacal nitrogen, respectively. The efficiency was enhanced to 91.1% for ammoniacal nitrogen from 21.7% after applying EO combined with NaOCl addition compared to individual NaOCl addition.