THE SYNTHESIS, CHARACTERIZATION, AND ELECTROCHEMICAL INVESTIGATION OF NOVEL THIO- AND ALKOXY-SUBSTITUTED BENZOQUINONE DERIVATIVES


Ibis C., Ayla S., Yavuz S.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.189, sa.4, ss.492-502, 2014 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 189 Sayı: 4
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1080/10426507.2013.829833
  • Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.492-502
  • Anahtar Kelimeler: p-Chloranil, thioalcohols, mercaptans, coumarine, QUINONES, BEHAVIOR
  • İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır

Özet

Novel thio- and alkoxy-substituted benzoquinone derivatives were synthesized from the reactions of p-chloranil (1) and related nucleophiles in a sodium carbonate (Na2CO3) solution of acetonitrile or in chloroform with Et3N. The structures of novel compounds were characterized by using microanalysis, FTIR, H-1 NMR, C-13 NMR, MS, CV, and fluorescence spectroscopy. [Supplementary materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements for the following free supplemental files: Additional text and figures.]