SYNTHESIS OF SOME NOVEL S- AND N,S-SUBSTITUTED CHLOROBUTADIENES
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.187, sa.8, ss.965-975, 2012 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 187 Sayı: 8
- Basım Tarihi: 2012
- Doi Numarası: 10.1080/10426507.2012.657313
- Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.965-975
- Anahtar Kelimeler: Morpholine, N,S-substituted nitrodiene, piperazine derivatives, polychloro-1,3-butadiene, thioether, THIOETHERS, AMINES, 2-NITROPENTACHLORO-1,3-BUTADIENE, DIENE
- İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır
Özet
Mono(thio)substituted nitrodienes were synthesized by reactions of 2-nitropentachloro- 1,3-butadiene with some thiols [(tert-butylbenzyl) thio-and 2,3,5,6-tetrafluorophenylthio-] either directly or in ethanol in the presence of sodium hydroxide. N,S-Substituted 1,3-butadienes were obtained from the reaction of the mono(thio)substituted nitrodienes with morpholine and some piperazine derivatives in dichloromethane. Also mono- and di(thio)substituted perchlorobutadienes were synthesized from the reactions of hexachloro-1,3-butadiene with o-aminothiophenol in ethanol in the presence of sodium hydroxide. The structures of the new compounds were characterized by microanalysis and spectroscopic data.