SYNTHESIS OF SOME NOVEL S- AND N,S-SUBSTITUTED CHLOROBUTADIENES

Ibis C., Gokmen Z., Cetin Z.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.187, sa.8, ss.965-975, 2012 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 187 Sayı: 8
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1080/10426507.2012.657313
  • Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.965-975
  • Anahtar Kelimeler: Morpholine, N,S-substituted nitrodiene, piperazine derivatives, polychloro-1,3-butadiene, thioether, THIOETHERS, AMINES, 2-NITROPENTACHLORO-1,3-BUTADIENE, DIENE
  • İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır

Özet

Mono(thio)substituted nitrodienes were synthesized by reactions of 2-nitropentachloro- 1,3-butadiene with some thiols [(tert-butylbenzyl) thio-and 2,3,5,6-tetrafluorophenylthio-] either directly or in ethanol in the presence of sodium hydroxide. N,S-Substituted 1,3-butadienes were obtained from the reaction of the mono(thio)substituted nitrodienes with morpholine and some piperazine derivatives in dichloromethane. Also mono- and di(thio)substituted perchlorobutadienes were synthesized from the reactions of hexachloro-1,3-butadiene with o-aminothiophenol in ethanol in the presence of sodium hydroxide. The structures of the new compounds were characterized by microanalysis and spectroscopic data.