REACTIONS OF 2-NITROPENTACHLORO-1,3-BUTADIENE WITH THIOLS AND MONO(THIO)-SUBSTITUTED 2-NITROBUTADIENES WITH DITHIOLS

IBIS C., SAYIL M. Ç.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.92, ss.39-44, 1994 (SCI-Expanded, Scopus) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 92
  • Basım Tarihi: 1994
  • Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier
  • Sayfa Sayıları: ss.39-44
  • İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır

Özet

Mono(thio)substituted compounds 3a-g and 3g are prepared by mixing 2-nitropentachlorobutadiene (1) with thiols 2a-g. 2-Nitrodiene 1 gives bis(thio)substituted 4c and tris(thio)substituted 5d by the reaction with the same thiols in EtOH containing sodium hydroxide. Cyclic thioethers 7a-b, acyclic thioether 9a and disulfide derivatives 8a-b are formed by the reaction of 3a with 1,2-ethanedithiol (6a) and 1,3-propanedithiol (6b) in EtOH in the presence of sodium hydroxide.