Trifluoromethylthiolation of Unsymmetrical lambda(3)-Iodane Derivatives: Additive-Free, Selective and Scalable Introduction of the SCF3 Group
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, sa.6, ss.1091-1094, 2016 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: Sayı: 6
- Basım Tarihi: 2016
- Doi Numarası: 10.1002/ejoc.201501623
- Dergi Adı: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.1091-1094
- İstanbul Üniversitesi-Cerrahpaşa Adresli: Hayır
Özet
The reaction of copper trifluoromethyl sulfide with diaryliodonium salts provides a straightforward pathway for the synthesis of aryl trifluoromethyl thioethers under mild reaction conditions and within short reaction times. High chemoselectivity was achieved by using mesityl as a leaving group. A large range of novel [(het)aryl](mesityl)iodonium salts underwent this reaction under the optimized conditions to give the desired products in moderate to good yields.